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PV equation of State of Antigorite: stability field of serpentines and seismicity in subduction zones

机译:antigorite状态的pV方程:蛇形场的稳定性和俯冲带的地震活动性

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摘要

Antigorite, the high-pressure variety of serpentine, is a major water carrier in subduction zones. Its equation of state, which controls its stability field at high pressure, was determined at ambient temperature up to 10 GPa by in situ synchrotron X-Ray diffraction in a diamond-anvil cell. No amorphization, phase transition or hysteresis were detected during compression or decompression. Compression is anisotropic, with the c axis twice as compressible as the others. A fit to the second order Birch-Murnaghan equation of state gave V 0 = 2926.23(50) Å3 and K 0 = 67.27(123) GPa. In antigorite the atomic assemblage is denser than in lizardite, which may influence phase stability. The antigorite K 0 value obtained here is significantly higher than currently assumed in thermodynamic databases. Antigorite P-T stability field is re-evaluated, with major dehydration reaction (and associated potential earthquake) loci occurring at lower pressures, and is found to be consistent with the latest experimental results.
机译:蛇纹石是高压蛇纹石,是俯冲带的主要水载体。它的状态方程在高压下控制其稳定场,是在环境温度高达10 GPa的条件下,通过金刚石-砧室中的原位同步加速器X射线衍射确定的。在压缩或减压过程中未检测到非晶化,相变或滞后现象。压缩是各向异性的,c轴的压缩度是其他轴的两倍。对二阶Birch-Murnaghan状态方程的拟合给出V 0 = 2926.23(50)Å3和K 0 = 67.27(123)GPa。在蛇纹石中,原子集合比在蜥蜴石中更密集,这可能会影响相稳定性。此处获得的反蛇毒K 0值明显高于当前在热力学数据库中假定的值。重新评估了防蛇毒的P-T稳定性场,在较低的压力下发生了主要的脱水反应(和相关的潜在地震)位点,发现与最新的实验结果一致。

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